(403)Copolymerization of α -Cl-methylacrylate and Acrylic Esters.
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چکیده
منابع مشابه
Molecular interaction studies of acrylic esters with 1-alcohols.
Hydrogen bonding between 1-alcohols and acrylic esters in n-heptane has been studied by FTIR spectroscopic method. The formation constant of the 1:1 complexes has been calculated using Nash method. The values of formation constant and free energy change vary with alcohol and ester chain length, which suggests that the strengths of the intermolecular O-H...O=C bonds are shown to be dependent on ...
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Room-temperature vulcanizing silicone and homopolymers of 2-hydroxyethyl methacrylate (HEMA) have been used to permanently inflate detachable balloons [1] . HEMA is preferred over silicone because it is less viscous and is water soluble. Goto et al. [2] described a commercially available (HEMA A, lnterventional Therapeutics, S. San Francisco, CA) polymerizing substance that includes HEMA as the...
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Eudragit RL (ERL) and Eudragit RS (ERS) are biocompatible cationic copolymers, pH-independent and insoluble in aqueous environment. In this study drug delivery system consisting of a capsule filled with floating pellets with verapamil hydrochloride (VH) is proposed. The release of VH in the stomach results in better solubility in an acid gastric environment in vivo and may result in greater amo...
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A variety of chiral N-phosphinyl α-imino esters have been synthesized for the first time from ketoesters and phosphinylamide, which were then reduced by L-selectride to give the corresponding N-phosphinyl-protected α-amino esters. The reduction proceeded very well with excellent chemical yields (88-98%) as well as high diastereoselectivities (96:4 to 99:1). Some of these products could be obtai...
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The aza-Michael addition of 1,2,3,6-tetrahydrophthalimide with symmetrical fumaric esters has been performed efficiently in a solvent-free system at 100 °C and using 1,4-diazabicyclo[2.2.2]octane (DABCO) as a base in the presence of tetrabutylammonium bromide (TBAB). The products were obtained in good to high yields within 2.5-7.0 h. This reaction worked well on linear alkyl fumarates and was n...
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1953
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.56.870